Real-time monitoring of marine ecosystems is crucial for global climate change research. In extreme marine environments such as the westerly regions in the Arctic and Antarctic, monitoring buoys and platforms often suffer from severe challenges, including insufficient energy supply, limited battery life, and difficult maintenance. Triboelectric nanogenerators (TENGs) offer a promising strategy for self-powered marine sensing. However, conventional tubular liquid–solid triboelectric nanogenerators (LS-TENGs) suffer from low efficiency of interfacial charge transfer due to limited contact area and excessive internal resistance, which restricts their output. In this study, a multi-tube nested liquid–solid triboelectric nanogenerator (MLS-TENG) is proposed, and the suitable filling ratio is determined through comparative experiments on structural parameters. This design significantly increases the effective contact area, reduces internal resistance, and improves synergistic charge transfer at multiple interfaces. Experimental results demonstrate that the MLSTENG exhibits substantially improved electrical output compared with the corresponding single-tube structures. When integrated with a power management module, the capacitor charging efficiency is improved by approximately 120 times. In real sea trials, an array composed of MLS-TENG units successfully drives a self-powered sensing system, achieving stable 4G transmission of environmental parameters. This work provides a scalable structural optimization strategy for constructing high-performance blue energy-harvesting self-powered nodes for the marine Internet of Things.
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